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Vibronic analysis of NLO spectra of PDA crystals and films

机译:PDA晶体和薄膜的NLO光谱的振动分析

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Abstract: A joint analysis of recent NLO spectra of polydiacetylene films and crystals is presented, using vibronic contributions in the Condon approximation and $pi@-electronic states from Pariser-Parr-Pople theory. Raman resonances are shown to be corrections to average excitations. An even-parity state above the photoconduction edge is found in two-photon absorption of PDA-PTS crystals and nondegenerate four-wave-mixing spectra of PDA- 4BCMU films. We incorporate linear and resonance Raman spectra in the joint NLO analysis and emphasize the different roles of electronic and vibrational contributions. !31
机译:摘要:利用Parander-Parr-Pople理论中的康登近似中的电子振动贡献和$ pi @-电子态,对聚二乙炔薄膜和晶体的NLO光谱进行了联合分析。拉曼共振被证明是对平均激发的校正。在PDA-PTS晶体的双光子吸收和PDA-4BCMU膜的非简并四波混合光谱中发现了光导边缘上方的偶校验状态。我们在线性NLO分析中纳入了线性和共振拉曼光谱,并强调了电子和振动贡献的不同作用。 !31

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