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High performance silver nanowire based transparent electrodes reinforced by EVA resin adhesive

机译:EVA树脂胶增强的高性能银纳米线基透明电极

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摘要

Transparent conducting films (TCFs) based electrodes are indispensable for most optoelectronic devices e.g. liquid crystal displayers, transparent touch panels, organic light-emitting diodes, and solar cells. Traditional TCF materials, such as indium tin oxide (ITO), have some inherent shortcomings, such as high-vacuum deposition process, high deposition temperature, relatively high cost, and brittleness. With the bloom of flexible and wearable electronics, flexible TCFs become more important than ever. Among various candidates, silver nanowires (AgNWs) based TCF draws more attentions than others for its superior electrical and optical properties. However there are still some challenges to be overcome, such as the poor electrical contact among the AgNWs and the weak mechanical contact between the AgNWs conducting networks and transparent substrate. In this work, combining the electrostatic spraying and Mayer rod coating processes, we have fabricated a high performance AgNWs based TCF with over 85% optical transmittance, less than 50 Ω/sq sheet resistance, and excellent adhesion to the substrate with the involvement of ethylene viny acetate (EVA) resin as the interlayer. This simple two steps process is also compatible with the roll-to-roll coating process, which can well address the challenges of low cost, high performance, flexibility and robustness.
机译:基于透明导电膜(TCF)的电极对于大多数光电子设备(例如光电器件)是必不可少的。液晶显示器,透明触摸屏,有机发光二极管和太阳能电池。传统的TCF材料,例如氧化铟锡(ITO),具有一些固有的缺陷,例如高真空沉积工艺,高沉积温度,相对较高的成本和脆性。随着柔性和可穿戴电子产品的兴起,柔性TCF变得比以往任何时候都更加重要。在各种候选材料中,基于银纳米线(AgNWs)的TCF因其卓越的电学和光学特性而受到了更多的关注。然而,仍然有一些挑战需要克服,例如AgNW之间的不良电接触以及AgNW导电网络与透明基板之间的机械接触较弱。在这项工作中,我们结合了静电喷涂和Mayer棒涂工艺,我们制造了一种高性能的基于AgNWs的TCF,其透光率超过85%,薄层电阻小于50Ω/ sq,并且在乙烯的作用下对基材具有出色的附着力醋酸乙烯酯(EVA)树脂作为中间层。这种简单的两步过程也与卷对卷涂布过程兼容,可以很好地应对低成本,高性能,灵活性和坚固性的挑战。

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