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Gold nanoparticle/PVDF polymer composite with improved particle dispersion

机译:具有改善的颗粒分散性的金纳米颗粒/ PVDF聚合物复合材料

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A substantial amount of work has been carried out in the area of dielectric nanocomposite materials. However, reported nanocomposite materials generally have disadvantages such as high dielectric loss mainly due to the nanoparticle agglomeration. Here, we present a novel nanocomposite material having polyvinylpyrrolidone (PVP) functionalized gold nanoparticles (5 nm in diameter) embedded inside a polyvinylidene fluoride (PVDF) host polymer. A homogeneous dispersion of gold nanoparticles with low particle agglomeration has been achieved, up to 5 wt % of nanoparticles. Fabricated nanoparticle polymer composite films showed the absence of voids and cracks. Also, no evidence of macro-phase separation of nanoparticles from the polymer phase was observed.
机译:在介电纳米复合材料领域已经进行了大量工作。然而,报告的纳米复合材料通常具有诸如高介电损耗的缺点,这主要归因于纳米粒子的团聚。在这里,我们介绍了一种新型的纳米复合材料,该材料具有嵌入聚乙烯基偏二氟乙烯(PVDF)主体聚合物中的聚乙烯吡咯烷酮(PVP)功能化的金纳米颗粒(直径5 nm)。已经实现了具有低颗粒团聚的金纳米颗粒的均匀分散体,其高达纳米颗粒的5重量%。制备的纳米颗粒聚合物复合膜显示没有空隙和裂缝。同样,也没有观察到纳米颗粒与聚合物相发生宏观相分离的迹象。

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