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Elastic Properties of Yttrium Doped Barium Zirconate

机译:钇掺杂钡锆酸的弹性性质

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Elastic properties are fundamental knowledge for structural designing. Under the development of proton-conducting ceramics fuel cells (PCFCs), there is no doubt about the importance of elastic properties. However, the systematic study about component materials of PCFCs has been insufficient, and obtained elastic properties cannot cover the entire operation conditions. Low sinterability and processability of solid electrolytes prevent from adopting conventional measuring method for high temperature metals. We therefore modified an ultrasonic transmission method for pellet type specimens and measured elastic properties in 10, 15, 20 mol% yttrium doped barium zirconate from room temperature to 700°C. The results indicated that elastic moduli such as Young's modulus and shear modulus gradually decrease with temperature rising to approximately 200°C and the slope became moderate over 400°C. Elastic moduli in BZY decreased by 30-40% from room temperature to 500°C. Observed temperature dependences are important basic properties for the structural designing of PCFCs.
机译:弹性物业是结构设计的基础知识。在质子导电陶瓷燃料电池(PCFC)的发展下,毫无疑问是弹性特性的重要性。然而,关于PCFC的组分材料的系统研究不足,获得的弹性性能不能覆盖整个操作条件。固体电解质的低烧结性和加工性可防止采用常规测量方法进行高温金属。因此,我们改变了用于颗粒型样品的超声波传输方法,并在10,15,20mol%的钇中测得的弹性性能从室温到700℃。结果表明,较年轻的模量和剪切模量如缺血模量随温度上升至约200℃的温度逐渐减小,并且斜率变为400℃。 BZY中的弹性模量从室温降低30-40%至500℃。观察到的温度依赖性是PCFC结构设计的重要基本性质。

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