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Chromate-Based Oxide Anodes for Low-Temperature Operating Solid Oxide Fuel Cells

机译:用于低温操作固体氧化物燃料电池的铬酸盐基氧化物阳极

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Doped-YCrO_(3-δ) ceramic oxides were investigated as potential anode materials for low-temperature solid oxide fuel cells (LT-SOFC, 400-650°C). The studied materials exhibited orthorhombic symmetry and one of the compositions showed an electrical conductivity of 1.7 and 3.5 S/cm at 600°C measured under reducing gases and air, respectively. Ni-GDC nanoparticles were introduced on the surface of the doped-YCrO_(3-δ) ceramic scaffold to achieve catalytic properties for H_2 oxidation. The electrochemical properties of the newly developed material were determined using symmetrical cells. Peak power density of 200 mW/cm~2 at 0.4 A/cm~2 was achieved at 650°C in H_2/3% H_2O using an electrolyte-supported SOFC.
机译:研究了掺杂的YCRO_(3-δ)陶瓷氧化物作为低温固体氧化物燃料电池(LT-SOFC,400-650℃)的潜在阳极材料。所研究的材料表现出正交对称性的对称性,其中一种组合物在降低气体和空气下分别在600℃下显示为1.7和3.5 s / cm的电导率。将Ni-GDC纳米颗粒引入掺杂YcRO_(3-δ)陶瓷支架的表面上,以实现H_2氧化的催化性质。使用对称电池测定新开发材料的电化学性质。使用电解质支持的SOFC在650℃下在650℃下在650℃下实现200mW / cm〜2的峰值功率密度。

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