APS Deposition of MnCo_2O_4 on Commercial Alloys K41X Used as Solid Oxide Fuel Cell Interconnect: The Importance of Post Heat-Treatment for Densification of the Protective Layer

摘要

The continuous contamination of the cathode with chromium released from metallic interconnects speeds up the degradation of the performance of the cell. For this reason, solid oxide fuel cell (SOFC) interconnects are coated with a dense protective layer. This layer plays the role of a diffusion barrier for the chromium evaporation at operating conditions. The deposition of a dense, gas tight and stable MnCo_2O_4 spinel layer on ferritic alloy using the atmospheric plasma spraying (APS) process is studied. The first experimental results show that the plasma spray process combined with an appropriate post thermal-treatment is suitable to form a dense spinel protective layer.