首页> 外文会议>IEEE Photovoltaic Specialists Conference >EFFECT OF SURFACE CLEANING ON PYRAMID SIZE OF RANDOMLY TEXTURED MONO CRYSTALLINE SILICON AND THE IMPACT ON SOLAR CELL EFFICIENCY
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EFFECT OF SURFACE CLEANING ON PYRAMID SIZE OF RANDOMLY TEXTURED MONO CRYSTALLINE SILICON AND THE IMPACT ON SOLAR CELL EFFICIENCY

机译:表面清洁对随机纹理单晶硅金字塔大小的影响及对太阳能电池效率的影响

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In this paper we report on the use of cleaning chemistry, SunSource 68 developed by Air Product Chemicals, Inc., (APCI) to control random texturing time and pyramid size on mono-crystalline silicon wafers. This chemistry is applied immediately after saw damage removal, which removes residues and acts as a catalyst to initiate texturing very rapidly. Due to rapid nucleation, the amount of IPA needed in the solution is very small and our texturing time is cut down by half. Thus the amount of silicon removed as a result of texturing is ~45% less than the standard texturing without the clean and this increases the texturing bath life. We have applied this cleaning chemistry before texturing and compared with the standard texturing process. The use of the cleaning solution has produced uniform pyramids across a wafer and from wafer to wafer, irrespective of wafer vendor. We found, repeatedly and reproducibly, ~0.5% efficiency improvement with the cells made in conjunction with the cleaning chemistry. This improvement resulted from a combination of lower weighted reflectance and narrow gridlines resulting from uniform and small pyramids associated with the cells using cleaning chemistry. We have demonstrated an 18.3% average efficiency large area (239 cm~2) cells on 2.6 Ω-cm CZ Si compared to 17.8% for the standard textured cells.
机译:在本文中,我们报告了使用清洁化学,Sunsource 68由空气产品化学品,Inc。(APCI)开发的Sunsource 68控制单晶硅晶片上的随机纹理时间和金字塔大小。在除去损伤后立即施加该化学,从而除去残留物并用作催化剂以非常快速地引发纹理。由于核心快速,解决方案所需的IPA量非常小,我们的纹理时间被削减了一半。因此,由于纹理的粘合剂除以〜45%而不是清洁的标准纹理,这增加了纹理浴寿命。在纹理之前,我们已应用此清洁化学,并与标准纹理过程相比。不管晶片供应商如何,清洁溶液的使用在晶片上并从晶片到晶片产生均匀的金字塔。我们发现,反复和可重复地,效率改善了〜0.5%,与清洁化学结合制成的电池。这种改进是由使用清洁化学与细胞相关的均匀和小金字塔产生的较低加权反射率和窄栅格的组合产生。我们已经展示了18.3%的平均效率大面积(239cm〜2)细胞,而标准纹理细胞的18.6Ω-cm CZ SI相比为17.8%。

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