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Preparation of antioxidative nano copper pastes for printed electronics application

机译:用于印刷电子应用的抗氧化纳米铜浆的制备

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Copper nanoparticles are alternative for silver and gold nanoparticles which are currently used in inkjet printing of conductive patterns because of the low price and high electrical conductivity. However, the serious impediment to using copper nanoparticles for conductive inks is their spontaneous oxidation. In the paper, the well-dispersed antioxidative copper pastes were prepared by dispersing the nanoparticles in an ethanol solution of lactic acid, and then deposited on glass slides. The resistivity of conductive copper films was 1.4×10−5 Ω·cm after annealing at 200 °C for 30 min. It was experimentally proved that lactic acid could react with the copper oxides surrounding Cu to form copper carboxylate, which was then reduced to Cu after annealing at 200 °C under nitrogen atmosphere. Furthermore, the copper film after annealing at 200 °C for 30 min under nitrogen atmosphere showed antioxidative characteristic.
机译:铜纳米粒子是银和金纳米粒子的替代品,由于其价格低廉,导电率高,目前已用于导电图案的喷墨印刷。然而,将铜纳米颗粒用于导电油墨的严重障碍是它们的自发氧化。在本文中,通过将纳米颗粒分散在乳酸的乙醇溶液中,然后分散在载玻片上,制备了分散良好的抗氧化铜浆。 200℃退火30min后,导电铜膜的电阻率为1.4×10 -5 Ω·cm。实验证明,乳酸可以与Cu周围的铜氧化物反应形成羧酸铜,然后在氮气氛下于200°C退火后将其还原为Cu。此外,在氮气氛下于200℃退火30分钟后的铜膜显示出抗氧化特性。

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