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Synthesis and properties of linear polyphosphazenes with different side groups

机译:不同侧基的线性聚磷腈的合成及性能

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@@In this paper, four linear polyphosphazenes with different side groups were synthesized by the reaction of poly(dichlorophosphazene) with their corresponding sodium salts. The poly (dichlorophosphazene) was obtained by the ringopening reaction of Hexachlorocyclotriphosphazene. The structures and properties of these polymers were characterized and the influence of their thermal performance was studied. The design of linear polyphosphazene structure is the flame-retardant application in rubber, plastic and polyester fiber, because the superiority of the structure is the good compatibility, high efficient flame resistance and non-migration et al for base polymer.
机译:在本文中,通过使聚二氯磷腈与其相应的钠盐反应,合成了四个具有不同侧基的线性聚磷腈。通过六氯环三磷腈的开环反应获得聚(二氯磷腈)。表征了这些聚合物的结构和性质,并研究了其热性能的影响。线性聚磷腈结构的设计是在橡胶,塑料和聚酯纤维中的阻燃应用,因为该结构的优越性是良好的相容性,高效的阻燃性以及对于基础聚合物的不迁移等。

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