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Effect of temperature on the crevice corrosion resistance of Ni-Cr-Mo alloys as engineered barriers in nuclear waste repositories

机译:温度对Ni-Cr-Mo合金作为核废料库中工程屏障的耐缝隙腐蚀性能的影响

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Ni-Cr-Mo alloys offer an outstanding corrosion resistance in a wide variety of highly corrosive environments. Alloys 625, C-22, C-22HS and HYBRID-BC1 are considered among candidates as engineered barriers of nuclear repositories. The objective of the present work was to assess the effect of temperature on the crevice corrosion resistance of these alloys. The crevice corrosion repassivation potential (E_(R.CREV)) of the tested alloys was determined by the Potentiodynamic-Galvanostatic-Potentiodynamic (PD-GS-PD) method. Alloy HYBRID-BC1 was the most resistant to chloride-induced crevice corrosion, followed by alloys C-22HS, C-22 and 625. E_(R.CREV) showed a linear decrease with temperature. There is a temperature above which Ercrev does not decrease anymore, reaching a minimum value. This E_(R.CREV) value is a strong parameter for assessing the localized corrosion susceptibility of a material in a long term timescale, since it is independent of temperature, chloride concentration and geometrical variables such as crevicing mechanism, crevice gap and type of crevice former.
机译:Ni-Cr-Mo合金在各种高度腐蚀的环境中均具有出色的耐腐蚀性。 625,C-22,C-22HS和HYBRID-BC1合金被认为是核储存库的工程屏障。本工作的目的是评估温度对这些合金耐缝隙腐蚀的影响。通过电位动力-恒静电-电位动力(PD-GS-PD)方法确定测试合金的缝隙腐蚀再钝化电位(E_(R.CREV))。 HYBRID-BC1合金对氯化物引起的缝隙腐蚀的抵抗力最强,其次是C-22HS,C-22和625合金。E_(R.CREV)随温度呈线性下降。有一个温度,在这个温度下Ercrev不再降低,达到最小值。该E_(R.CREV)值是长期评估材料局部腐蚀敏感性的重要参数,因为它与温度,氯化物浓度和几何变量(例如,缝隙机制,缝隙和缝隙类型)无关前任的。

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