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Effect of temperature on the crevice corrosion resistance of Ni-Cr-Mo alloys as engineered barriers in nuclear waste repositories

机译:温度对核垃圾储存库中镍钼合金作为工程障碍的缝隙耐腐蚀性的影响

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Ni-Cr-Mo alloys offer an outstanding corrosion resistance in a wide variety of highly corrosive environments. Alloys 625, C-22, C-22HS and HYBRID-BC1 are considered among candidates as engineered barriers of nuclear repositories. The objective of the present work was to assess the effect of temperature on the crevice corrosion resistance of these alloys. The crevice corrosion repassivation potential (E_(R.CREV)) of the tested alloys was determined by the Potentiodynamic-Galvanostatic-Potentiodynamic (PD-GS-PD) method. Alloy HYBRID-BC1 was the most resistant to chloride-induced crevice corrosion, followed by alloys C-22HS, C-22 and 625. E_(R.CREV) showed a linear decrease with temperature. There is a temperature above which Ercrev does not decrease anymore, reaching a minimum value. This E_(R.CREV) value is a strong parameter for assessing the localized corrosion susceptibility of a material in a long term timescale, since it is independent of temperature, chloride concentration and geometrical variables such as crevicing mechanism, crevice gap and type of crevice former.
机译:Ni-Cr-Mo合金在各种高度腐蚀性环境中提供出色的耐腐蚀性。作为核储存库的工程障碍,考虑了合金625,C-22,C-22HS和Hybrid-BC1。本作工作的目的是评估温度对这些合金的缝隙耐腐蚀性的影响。通过电位动力学 - 渗透型电位(PD-GS-PD)方法测定测试合金的缝隙腐蚀回归电位(E_(R.CREV))。合金杂交BC1对氯化物诱导的缝隙腐蚀最具耐抗性,其次是合金C-22HS,C-22和625. E_(R.CREV)显示与温度的线性降低。高于ercrev不再减少的温度,达到最小值。该E_(R.CREV)值是用于评估长期时间尺度的材料的局部腐蚀敏感性的强大参数,因为它与温度,氯化物浓度和几何变量无关,例如裂缝机构,缝隙间隙和缝隙类型以前的。

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