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Rheological characterization of carbon black-filled polybutylene terephthalate

机译:炭黑填充的聚对苯二甲酸丁二醇酯的流变特性

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The rheological properties of carbon black (CB)/polybutylene terephthalate (PBT) composites were investigated by rheological experiments, focusing on polymer-CB particles interaction. With increasing CB loading, the storage modulus G' gradually oversteps the loss modulus G″ at low frequency, which indicate the microstructure of melt composites takes transition from solid-like to gel-like behavior. In low shear rate region, the elevating temperature causes the increases of the storage modulus G' and complex viscosity η* because of the strong interaction in the CB/PBT composite.
机译:通过流变实验研究了炭黑(CB)/聚对苯二甲酸丁二醇酯(PBT)复合材料的流变性能,重点是聚合物-CB颗粒的相互作用。随着CB负载的增加,储能模量G'在低频下逐渐超过损耗模量G'',这表明熔融复合材料的微观结构从固态转变为凝胶态。在低剪切速率区域,由于CB / PBT复合材料之间的强相互作用,升高的温度导致储能模量G'和复数粘度η*增大。

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