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Colloidal Mikado: Rheology and Structure of Thermoreversible Gels of Sticky Rod-Like Particles

机译:胶体Mikado:粘性棒状颗粒的热可逆凝胶的流变学和结构

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The assembly of rod-like particles by weak attractive inter-actions is important for the properties of several soft biological materials as wellas in tailoring the properties of colloidal gels in a variety of applications. Under-standing the link between the physicochemical parameters such as size and aspectratio, volume fraction, interparticle forces with the resulting microstructure andthe rheological response remains however challenging. It is often dicult to obtaina good control over these parameters due to the lack of suitable model systems.In the present work a model rod-like fd-virus particle has been surface modiedwith a thermoreversible polymer poly(N-isoproplyacrlyamide). The repulsive andattractive contributions to the overall interaction potential can be varied indepen-dently by changing the ionic strength and the temperature. The eects of thesechanges on the strength and structure of the gel have been studied near the geltransition using a combination of rheological and scattering measurements. Theresults show that for these thermoreversible 'sticky' rod systems, the variations ofthe structure in the gelled state are relatively weak, with the gel strength mainlybeing controlled by the relative magnitudes between the attractive and repulsivecontributions and the volume fraction, the anisotropic nature of the electrostaticinteractions seems to have a minor eect.
机译:棒状颗粒通过弱的吸引力相互组装 作用对于几种软生物材料的性能也很重要 如在各种应用中定制胶体凝胶的特性。在下面- 站在物理化学参数(例如大小和长宽比)之间的链接 比,体积分数,粒子间作用力以及产生的微观结构和 流变响应仍然具有挑战性。通常很难获得 由于缺乏合适的模型系统,因此无法很好地控制这些参数。 在本工作中,对模型杆状fd-病毒颗粒进行了表面修饰 与热可逆的聚合物聚(N-异丙基丙烯酰胺)。排斥和 对整体交互潜力的吸引人的贡献可以独立地变化- 通过改变离子强度和温度来实现这些的效果 已经在凝胶附近研究了凝胶强度和结构的变化 流变和散射测量相结合的过渡。这 结果表明,对于这些热可逆的“粘性”杆系统, 胶凝状态的结构相对较弱,主要是胶凝强度 由吸引和排斥之间的相对大小控制 贡献和体积分数,静电的各向异性 互动似乎没有什么影响。

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