PREPARATION AND PROPERTIES OF ENERGETIC TRIMETHYL-AMINE DERIVATIVES

摘要

Tris-(5-nitrotetrazol-2-ylmethyl)amine was prepared and fully characterized using DSC, bomb calorimetry, as well as vibrational, multinuclear NMR spectroscopy, and X-ray diffraction. Its properties were compared with the very energetic tris(azidomethyl)amine and displayed significant lower sensibilities. The structure of tris(azidomethyl)amine was calculated at the B3LYP/6-31G(d) level of theory.