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Activity and stability of Ni supported activated carbon for catalytic ozonation of p-chlorobenzoic acid

机译:负载镍的活性炭对氯苯甲酸催化臭氧化的活性和稳定性

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@@1. Background of the research Heterogeneous catalytic ozonation, a novel alternative to traditional AOPs, has received wide interest as a promising technology for removing refractory organic pollutants in water. Activated carbon presents a large surface area where organic pollutants can be adsorbed, while ozone readily destroys adsorbed aromatic molecules, helping to regenerate activated carbon adsorption capacity. p-chlorobenzoic acid (p-CBA) is an important intermediate for pesticides, pharmaceutics and dye. Due to its bio-recalcitrant property, p-CBA accumulates in the environment as intermediate during biodegradation of chlorinated aromatics like polychlorinated biphenyls. In the present work, p-CBA was chosen as a model compound to analyze catalytiC activity of activated carbon prepared from coconut hull and Ni supported activated carbon (Ni/AC) catalyst.
机译:@@ 1。研究背景非均相催化臭氧化技术是传统AOP的一种新型替代物,作为一种去除水中难降解有机污染物的有前途的技术而受到了广泛的关注。活性炭的表面积很大,可以吸收有机污染物,而臭氧很容易破坏吸附的芳香分子,从而有助于再生活性炭的吸附能力。对氯苯甲酸(p-CBA)是农药,药物和染料的重要中间体。由于其具有生物抑制性,因此对位CBA在氯化芳族化合物(如多氯联苯)的生物降解过程中作为中间体积累在环境中。在本工作中,选择p-CBA作为模型化合物,以分析由椰子壳和Ni负载的活性炭(Ni / AC)催化剂制备的活性炭的催化活性。

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