ON THE REACTION OF TRINITROAROMATIC COMPOUNDS WITH 4-AMINO-1,2,4-TRIAZOLE

摘要

Treatment of some 2,4,6-trinitrophenyl compounds with 4-amino-1,2,4-triazole in the presence of sodium methoxyde in Me_2SO leads to competing reactions - nucleophilic aromatic substitution and vicarious replacement of hydrogen.4-(2,4,6-trinitrophenyl)amino-1,2,4-triazole and polyamino trinitrobenzene derivatives are formed. Current research analyzes the influence of the nature of the substitute on the speed and direction of reaction.