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High-pressure oxygenation of thin-wall YBCO single-domain samples

机译:薄壁YBCO单畴样品的高压氧合

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The oxygen annealing of ReBCO bulk material, necessary to achieve superconducting properties, usually induces micro- and macro-cracks. This leads to a crack-assisted oxygenation process that allows oxygenating large bulk samples faster than single crystals. But excellent superconducting properties are cancelled by the poor mechanical ones. More progressive oxygenation strategy has been shown to reduce drastically the oxygenation cracks. The problem then arises to keep a reasonable annealing time. The concept of bulk Y123 single-domain samples with thin-wall geometry has been introduced to bypass the inherent limitation due to a slow oxygen diffusion rate. But it is not enough. The use of a high oxygen pressure (16 MPa) enables to speed up further the process. It introduces a displacement in the equilibrium phase diagram towards higher temperatures, i.e., higher diffusion rates, to achieve a given oxygen content in the material. Remarkable results were obtained by applying such a high pressure oxygen annealing process on thin-wall single-domain samples. The trapped field of 16 mm diameter Y123 thin-wall single-domain samples was doubled (0.6T vs 0.3T at 77K) using an annealing time twice shorter (about 3 days). The initial development was made on thin bars. The advantage of thin-wall geometry is that such an annealing can be applied directly to a much larger sample.
机译:ReBCO块状材料的氧退火是实现超导性能所必需的,通常会引起微裂纹和大裂纹。这导致了裂纹辅助的充氧过程,与单晶相比,该过程可以更快地充氧大块样品。但是优异的超导性能却被较差的机械性能所抵消。已显示出更先进的充氧策略可大大减少充氧裂纹。然后出现的问题是保持合理的退火时间。引入具有薄壁几何形状的块状Y123单域样品的概念是为了避免由于氧扩散速度慢而固有的局限性。但这还不够。高氧气压力(16 MPa)的使用可以进一步加快该过程。它在平衡相图中向较高的温度(即较高的扩散速率)引入位移,以实现材料中给定的氧含量。通过在薄壁单畴样品上应用这种高压氧退火工艺获得了显着的结果。使用短两倍的退火时间(约3天),将直径为16毫米的Y123薄壁单畴样品的俘获场加倍(0.6T对77K时为0.3T)。最初的开发是在细条上进行的。薄壁几何形状的优点是可以将这种退火直接应用于更大的样品。

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