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Low Hydroxyl Number Polyester Polyols for Lamination

机译:用于层压的低羟值聚酯多元醇

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摘要

In 2005, the polyiso lamination industry experienced a shortage of polymeric isocyanate. This shortage also brought rising costs of isocyanate. To counteract the situation, the polyiso laminators looked to reducing isocyanate consumption. The polyester polyol producers were asked to develop polyester polyols in the 200 OH NO range as this would save about 7 to 10% of the isocyanate usage. Reducing the OH NO of a polyester polyol alone will cause the 2.5 index foam to be softer and depending on the polyester polyols could reduce the dimensional stability of the foams. Additionally, the lower OH NO can also cause deterioration in the thermal stability of the foam if the polyol is not designed properly. Oxid will show through laboratory work that the minimum OH NO should be 200; that as the OH NO is reduced, the functionality of the polyol should be increased to minimize a reduction in dimensional stability; and that the aromatic content should be increased to improve thermal stability.
机译:2005年,聚异氰酸酯层压行业经历了聚合异氰酸酯的短缺。这种短缺也带来了异氰酸酯成本的上涨。为了应对这种情况,多异氰酸酯层压机希望减少异氰酸酯的消耗。要求聚酯多元醇生产商开发200 OH NO范围内的聚酯多元醇,因为这将节省约7%至10%的异氰酸酯用量。单独降低聚酯多元醇的OH NO将导致2.5指数泡沫更软,并且取决于聚酯多元醇会降低泡沫的尺寸稳定性。另外,如果多元醇设计不当,较低的OH NO也会导致泡沫塑料的热稳定性变差。氧化将通过实验室工作表明,最低OH NO应为200。随着OH NO的还原,应增加多元醇的官能度,以最大程度地降低尺寸稳定性;并且应当增加芳族含量以改善热稳定性。

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