首页> 外文会议>Fourth Joint Meeting of the U.S. Sections of the Combustion Institute: Western States, Central States, Eastern States: Abstracts >Effect of HBr addition on NO production during charoxidation at pulverized coal combustion conditions
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Effect of HBr addition on NO production during charoxidation at pulverized coal combustion conditions

机译:煤粉燃烧条件下添加HBr对焦氧化过程中NO生成的影响

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The ability of radical scavengers, such as iodine, to affect the yield of nitrogen-containingspecies has previously been used to give insight on the mechanism of char-N conversionto NO during fluidized bed coal combustion. This paper presents preliminarilyexperimental results on the effect that the addition of a radical scavenger (HBr) has onthe conversion of char-N to NO for pulverized coal particles at gas temperatures of 1173K and 1423 K and with two different background NO concentrations (45 ppm and 500ppm dry). The experiments show an increase in CO concentration in the presence of HBrat 1173 K and no change at 1423 K. The change in NO concentration after HBr additionis positive at 1173 K and negative at 1423 K. Future experiments and application of a detailedreacting particle model are required to explain the mechanism for the variation ofNO concentration after HBr addition.
机译:自由基清除剂(如碘)影响含氮量的能力 物种以前曾被用来提供有关char-N转化机理的见解 在流化床煤燃烧过程中变为NO。本文初步介绍 自由基清除剂(HBr)的添加对实验产生影响的实验结果 气体温度为1173时煤粉将char-N转化为NO K和1423 K以及两种不同的背景NO浓度(45 ppm和500 ppm干燥)。实验表明,在存在HBr的情况下,CO浓度会增加 在1173 K时没有变化,在1423 K时没有变化。添加HBr后NO浓度的变化 在1173 K时为正,在1423 K时为负。详细的未来实验和应用 需要使用反应粒子模型来解释变化的机理 加入HBr后NO浓度升高。

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