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Physio-Chemical Characterisation of Vegetable Oils and Preliminary Test Results ofVegetable-Oil-Based Muds

机译:植物油的理化特性和基于植物油的泥浆的初步测试结果

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Mineral oil-based drilling muds are toxic, not readilybiodegradable and thus have cumulative impact on terrestrial,coastal and marine habitats. The base fluid for mineral oil-basedmud development has limited source of supply.Vegetable oils are renewable, highly biodegradable, can beproduced as per industry demand and thus could be a suitablecandidate for development of a highly biodegradable oil-basedmud with a sustainable source of supply. They have higherflash and fire points, better thermal stability, no detrimentalimpact on the surrounding environment and are much lesshazardous compared to mineral oils. Due to biodegradablenature of vegetable oils, drill cuttings will have noenvironmental impact if the cuttings are disposed directly to thesurrounding environments. Due to non-reactive nature ofvegetable oils with clays and shales, their technicalperformance in maintaining borehole stability is comparable tomineral oil. On the other hand, due to readily biodegradablenature and negligible toxicity effect, vegetable oil-based mudperformance should be comparable to water-based mud fromenvironmental point of view. Hence, vegetable oil-based mudcould be a potential solution to meet the current as well asfuture technical and environmental challenges.An invert emulsion mud was developed using a blend ofvegetable oil to study the rheological and filtration propertiesand evaluate its suitability for oil well drilling. Initial mudformulation indicates that development of a viable OBM is notpossible using the conventional approach due to the highinherent viscosity of vegetable oils and significant thermaldegradation at high temperature. However, processing andtreatment of vegetable oils lead to the formulation of avegetable oil-based mud with desirable rheological propertiesand excellent thermal stability. Preliminary test results indicatethat the processed vegetable oil-based mud produces suitablelow end rheological properties including gelling characteristics.Thermal conditioning of the mud at 150 °C for 16 hours indicates no significant changes in the rheological properties ofthe mud. The high thermal characteristics of vegetable oilsindicate their safe operation for all practical range oftemperatures.
机译:矿物油基钻井液有毒,不易产生 可生物降解的,因此对陆地产生累积影响, 沿海和海洋生境。矿物油基油 泥浆开发的供应来源有限。 植物油是可再生的,高度可生物降解的,可以 根据行业需求生产,因此可能是合适的 高度可生物降解的石油基开发的候选者 具有可持续供应来源的泥浆。他们有更高 闪点和着火点,更好的热稳定性,无害 对周围环境的影响小得多 与矿物油相比危险。由于可生物降解 植物油的性质,钻屑将没有 如果将碎屑直接丢弃到环境中,则会对环境造成影响 周围的环境。由于非反应性 带有泥土和页岩的植物油,其技术 保持井眼稳定性的性能可与 矿物油。另一方面,由于易于生物降解 性质和可忽略的毒性作用,植物油基泥浆 性能应可与水性泥浆相比 环境的观点。因此,植物油基泥浆 可能是满足当前以及未来的潜在解决方案 未来的技术和环境挑战。 反相乳液泥浆是使用以下物质的混合物开发的: 植物油以研究流变学和过滤性能 并评估其在油井钻井中的适用性。初始泥 配方表明可行的OBM的开发并非如此 由于高,可以使用常规方法 植物油的固有粘度和显着的热 在高温下降解。但是,处理和 植物油的处理导致配方的形成 具有理想流变性能的植物油基泥浆 以及出色的热稳定性。初步测试结果表明 加工过的植物油基泥产生合适的 低端流变特性,包括胶凝特性。 泥浆在150°C下进行16个小时的热调节,表明其流变特性没有明显变化。 泥。植物油的高热特性 指出他们在所有实际范围内的安全操作 温度。

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