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GETTERING AND PASSIVATION OF RECOMBINATION CENTRESIN N-TYPE MULTICRYSTALLINE SILICON

机译:N型多晶硅的重组中心的吸收与钝化

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Area-averaged carrier lifetimes of 200 μs in n-type block-cast multicrystalline silicon (mc Si) and40 μs in n-type edge-defined film-fed grown silicon (EFG Si) have been measured in the as-grown state. These lifetimevalues are about one order of magnitude higher compared to lifetimes typically measured in as-grown p-type mcand EFG Si and they were found to be perfectly stable under illumination. Phosphorus gettering improved the lifetimesin both types of material. A subsequent bulk hydrogenation step was found to be particularly effective in n-typemc Si, resulting in exceptionally high area-averaged lifetimes of 700 μs, with local lifetimes exceeding 1 ms. Importantly,no low-lifetime regions could be detected after hydrogenation. To our knowledge, a lifetime distribution of theobserved outstanding homogeneity has not been observed before in any block-cast mc Si material. Finally, we demonstratethe feasibility of easy-to-fabricate n+np+ solar cells featuring a screen-printed rear-junction Al-p+ emitter. Inour first cell batches we have achieved efficiencies up to 16.0 % on n-type monocrystalline silicon and efficiencies upto 11.8 % on n-type mc Si, demonstrating the potential of the developed low-cost cell process on n-type silicon materials.
机译:在n型块铸多晶硅(mc Si)和 在生长状态下,已测量了40μs的n型边缘界定的薄膜喂养生长的硅(EFG Si)。这些一生 与通常在成年p型mc中测得的寿命相比,该值约高一个数量级 和EFG Si,发现它们在光照下非常稳定。吸磷可延长使用寿命 在两种类型的材料中。发现随后的本体氢化步骤在n型反应中特别有效 mc Si,因此具有700μs的极高面积平均寿命,局部寿命超过1 ms。重要的, 氢化后未检测到低寿命区域。据我们所知, 据观察,在任何块铸mc Si材料中都没有观察到出色的均质性。最后,我们演示 具有丝网印刷后结Al-p +发射极的易于制造的n + np +太阳能电池的可行性。在 我们的第一批电池,我们在n型单晶硅上的效率达到了16.0%,并且效率提高了 在n型mc Si上达到11.8%的百分比,这表明了在n型硅材料上开发低成本电池工艺的潜力。

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