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FCC SO_x EMISSION REDUCTION: OPTIMIZATION OF ADDITIVES USE

机译:FCC SO_x排放量减少:添加剂使用的优化

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Silica inactivation of SO_3 absorbing sites is mentioned in the literature as the chief mechanism behind SOx additive deactivation, and steaming of mixtures of FCC catalyst with SOx additives is recommended prior to evaluation. The pilot riser experiments have shown that deactivation is very fast compared to the actual FCC catalyst and may calculated from the SO_2 base line level alone. From these results it is clear that steaming techniques developed to speed the slow mechanism of FCC catalyst deactivation are unsuitable for SOx additives, as they accelerate the wrong deactivation process. Therefore, SOx additives should be tested with no previous treatment in order to correctly evaluate their performance.
机译:文献中提到SO_3吸收位点的硅胶失活是SOx添加剂失活的主要机理,建议在评估之前将FCC催化剂与SOx添加剂的混合物汽化。中试立管实验表明,与实际的FCC催化剂相比,失活速度非常快,可以仅从SO_2基线水平计算得出。从这些结果可以明显看出,为加速FCC催化剂失活的慢速机理而开发的蒸汽处理技术不适用于SOx添加剂,因为它们会加速错误的失活过程。因此,SOx添加剂应在不进行任何前处理的情况下进行测试,以正确评估其性能。

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