首页> 外文会议>59th Society of Plastics Engineers Annual Conference >MULTI-COMPONENT BLENDS BASED ON POLYAMIDE 6 AND STYRENIC POLYMERS
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MULTI-COMPONENT BLENDS BASED ON POLYAMIDE 6 AND STYRENIC POLYMERS

机译:基于聚酰胺6和苯乙烯聚合物的多组分共混物

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Reactive and non-reactive blends of polyamide 6 (PA6) with different styrenic based polymers [acrylonitrile-butadiene-styrene terpolymer (ABS) and styrene-acrylonitrile copolymer (SAN)] were made on a twin screw extruder under similar processing conditions and blend composition. Effect of reactive compatibilizer on thermal, morphological and rheological properties were studied using DSC, SEM and a parallel plate oscillation rheometer. It was found that the reactive blends have lower crystallization rate and nucleation ability but higher melt viscosity with co-continuous morphology, whereas the uncompatibilized blends have higher crystallization rate and nucleation ability but lower melt viscosity and form disperse and/or coarse co-continuous morphology.
机译:聚酰胺6(PA6)与不同的苯乙烯基聚合物[丙烯腈-丁二烯-苯乙烯三元共聚物(ABS)和苯乙烯-丙烯腈共聚物(SAN)]的反应性和非反应性共混物是在双螺杆挤出机上以相似的加工条件和共混物组成制成的。使用DSC,SEM和平行板振荡流变仪研究了反应性增容剂对热,形态和流变性能的影响。发现反应性共混物具有较低的结晶速率和成核能力,但熔体粘度较高且具有共连续形态,而不相容的共混物具有较高的结晶速率和成核能力但熔体粘度较低并形成分散和/或粗糙的共连续形态。

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