Kinetics of Hydroformylation of Propylene Using Water-Soluble Rhodium Complex Catalyst

摘要

The kinetics of RhCl(CO)(TPPTS)_2/TPPTS catalyzed hydroformylation of C_3H_6 has been studied by orthogonal experiments. The effects of temperature, partial pressure of C_3H_6, H_2 and CO, rhodium concentration and TPPTS ligand concentration on the initial rate were determined by the margin and variance analyses. Several empirical rate equations were also proposed to represent the experimental data.