首页> 外文会议>Conference on laser techniques for state-selected and state-to-state chemistry >Isotopic branching ratios in reaction of O(1D) with hydrogen propane and 2-propylchloride and in VUV photodissociation
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Isotopic branching ratios in reaction of O(1D) with hydrogen propane and 2-propylchloride and in VUV photodissociation

机译:O(1D)与丙烷氢和2-丙基氯的反应和VUV光解离中的同位素支化比

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Abstract: ergized sufficiently either vibrationally or electronically, a molecule, RH, can dissociate to form H atoms and radicals. By partial deuteration of the molecule, one obtains information on isotope- and site-specific reactions, if they occur. We have studied reactions of O($+1$/D) with hydrogen, alkanes and alkyl chlorides that are partially deuterated, in addition to vacuum ultraviolet (VUV) photodissociation of these molecules. !12
机译:摘要:RH分子在振动或电子作用下均能充分施加能量,它可以解离形成H原子和自由基。通过分子的部分氘化,可以获得有关同位素和位点特异性反应的信息(如果发生的话)。我们研究了O($ + 1 $ / D)与氢,烷烃和烷基氯化物的部分氘化反应,以及这些分子的真空紫外线(VUV)光解离。 !12

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