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Thermophysical properties and microstructure of short carbon fibre reinforced Cu-matrix composites made by electroless copper coating or powder metallurgical route respectively

机译:化学镀铜或粉末冶金法制备的短碳纤维增强铜基复合材料的热物理性质和微观结构

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C fibre reinforced Cu matrix composites have the interesting properties of Cu, i.e. thermal and electrical conductivities, but the properties of the C fibre, i.e. small CTE, dominate mechanical behaviour. As desired composite properties can be obtained by selecting the amount and type of C fibres, it is suitable for electronic applications such as special heat sinks. Cu matrix composites with high conducting short fibres are a promising research field. Short C fibre reinforced Cu composites were made by hot-pressing of Cu coated C fibres chopped into different lengths (60 /spl mu/m-2 mm). By using electroless Cu coating-based production, a good fibre distribution in the matrix and good interfacial contact were obtained. The fibre length distribution strongly influences composite properties. During hot pressing, the C fibres take on a preferred orientation in a plane perpendicular to the hot pressing direction. Within this plane, fibre orientation is random. C fibre volume content was varied in a 38-64 vol.% range. The composite microstructures were studied by SEM and optical microscopy. Measured thermal conductivity and CTE were compared with microstructural results and results from mathematical models. The composites have thermal conductivity of about 250-300 W/mK in two dimensions and about 140 W/mK in the third dimension. The CTE can be tailored in a range of 4-10 ppm/K by changing the C fibre content. The relatively low density of 4-6 g/cm/sup 3/ is also important where weight reduction is desired. The results are compared with composites produced by powder metallurgical methods and those made with low conducting short C fibres.
机译:C纤维增强的Cu基复合材料具有有趣的Cu性质,即热导率和电导率,但是C纤维的性质,即小的CTE,支配着机械性能。由于可以通过选择C纤维的数量和类型来获得所需的复合性能,因此它适用于电子应用,例如特殊的散热器。高导电短纤维铜基复合材料是一个有前途的研究领域。短C纤维增强的Cu复合材料是通过将切成不同长度(60 / spl mu / m-2 mm)的Cu涂层C纤维热压制成的。通过使用基于化学镀铜的生产,获得了基体中良好的纤维分布和良好的界面接触。纤维长度分布强烈影响复合材料的性能。在热压期间,C纤维在垂直于热压方向的平面上具有优选的取向。在该平面内,纤维方向是随机的。 C纤维的体积含量在38-64体积%的范围内变化。通过SEM和光学显微镜研究了复合材料的微观结构。将测得的热导率和CTE与微观结构结果和数学模型的结果进行了比较。该复合材料在两个维度上具有约250-300W / mK的热导率,而在第三维度上具有约140W / mK的热导率。通过更改C纤维含量,可以将CTE调整为4-10 ppm / K的范围。在需要减轻重量的情况下,4-6 g / cm / sup 3 /的相对较低的密度也很重要。将该结果与通过粉末冶金方法生产的复合材料以及使用低导电短C纤维制成的复合材料进行了比较。

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