The Effect of Power Ultrasound in the Production of Synthetic Rutile by the Becher Process

摘要

Power ultrasound may be applied to enhancing the processing of minerals. The enhanced performance is achieved through the very localised high-energy release at the mineral surface from the collapse of cavitation bubbles produced by power ultrasound. This gives rise to two effects: initially, the rapid cleaning of mineral surfaces - of oxidation products and coatings of fine adhering gangue minerals - and the attenuation of the boundary layer at the mineral surface during leaching, which allows fresh leachant to contact the surface more readily. Work carried out at CSIRO in conjunction with Tiwest Joint Venture has demonstrated that it is feasible to apply ultrasound to the leaching process in order to enhance the removal of contaminating minerals. When applied to the production of synthetic rutile from reduced ilmenite produced by the Becher process, the use of ultrasound proved beneficial to both the aeration and the final acid leach process. The effect of ultrasound was less marked in the case of the aeration process, once the method of introducing and dispersing the air was optimised. In the subsequent acid leaching step of the Becher process it was found that the application of power ultrasound could reduce leaching time to about one quarter of the time required when only agitation was employed. Projected capital and operating costs, based on currently available commercial equipment, are also presented, and indicate that the use of ultrasound is commercially as well as technically feasible.