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Thermodynamical and structural aspects of holographic recording in photopolymers

机译:光敏聚合物中全息记录的热力学和结构方面

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Abstract: THe process of holographic recording in the liquid photopolymer compositions (PPC), which contain a photopolymerizable component, an initiating system and a neutral component, is described in the frame of the phase separation of the origin mixture. Experiments were performed to determine the dependence of efficiency of recording and lightsensitivity of material on the thermodynamical compatibility of the system polymer-neutral component, kinetic parameters of the polymerization process and the diffusion mass-transport, supported the formation of holograms. The two-phase structure of holograms in PPC has been observed with help of fluorescent probe method. The average size of the microphase particles has been determined. The effect of photopolymer heterogeneity on the noise characteristics of holograms and resolution of recording composition has been shown. !27
机译:摘要:在原始混合物相分离的框架中,描述了在包含光致聚合组分,引发体系和中性组分的液态光聚合物组合物(PPC)中进行全息记录的过程。进行实验以确定材料的记录效率和光敏性对体系聚合物中性组分的热力学相容性,聚合过程的动力学参数和扩散质量传输的依赖性,从而支持全息图的形成。借助荧光探针法已观察到PPC中全息图的两相结构。已经确定了微相颗粒的平均尺寸。已经显示了光聚合物异质性对全息图的噪声特性和记录组合物的分辨率的影响。 !27

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