Cyanide-Treated Fe(Ⅲ) Porphyrins as an Electrocatalytic Material for Selective H_2S Oxidation

摘要

Electrodeposited Fe(Ⅲ) meso-Tetra(4-carboxyphenyl) porphyrin with cyanide ligands coordinated to the central iron ion is being investigated as a possible material capable of selectively oxidizing H_2S in the presence of CO and NO in physiologically relevant solutions. Preliminary results suggest this to be a very attractive material as it oxidizes H_2S at low potentials while exhibiting minimal activity towards both CO and NO. However certain results suggest that the Fe may not be completely coordinated with cyanide ligands. This may explain the limitations of the material at elevated H_2S concentrations and imperfect selectivity over the interfering gases. Additionally, a cathodic-post run treatment is suggested in order to maintain the electrochemical activity of the porphyrin-modified electrode surface by stripping any S° that deposits on the electrode surface during the H_2S oxidation.