60FULLERENE FLUORINATION BY MOLECULAR FLUORINE IN MnF_3(s) MATRIX

摘要

[60] fullerene fluorination by molecular fluorine in MnF_3 matrix was studied in temperature range of 500-600K. It was established that under these fluorination conditions the gaseous mixture was enriched with higher fluorofullerenes. The total content of C_(60)F_(42), C_(60)F_(44), C_(60)F_(46) in mixture was more than 80% at 500 K, while C_(60)F_(44) content being 54%. Partial pressures of fluorination products and their yields were calculated based on the experimental data.