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Optical properties of semiconducting iron disilicide thin films

机译:半导体二硅化铁薄膜的光学性质

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Abstract: The iron silicides samples were formed by annealing of iron films evaporated onto silicon wafers and capped with either amorphous silicon or SiO$-x$/ thin overlayers. Semiconducting FeSi$-2$/ phase is formed by annealing at the temperatures from 550 degrees to 850 degrees. The optical properties of the FeSi$-2$/ layers have been deduced from reflectance and transmittance measurements carried out in the temperature range of 77-380K. The spectral dependence of the absorption coefficient favors direct allowed transitions with forbidden energy gap of 0.87eV at the room temperate. The application of a simple three-parameter semiempirical formula to the temperature dependence of the direct energy gaps leads to the following best fit parameters: the band gap at zero temperature E$-g$/(0) $EQ 0.895 $POM 0.0037eV, the dimensionless coupling parameter S $EQ 2.01 $POM 0.27, and the average phonon energy. By examining all the reported triplets of parameters for $beta@-FeSi$-2$/ fabricated by different techniques and thermal processes, an obvious discrepancy can be found for the lattice coupling parameter and average phonon energy, although the bandgaps at 0K are very similar. Unlike the theoretical prediction and the earlier reported result our results do not show any evidence of a particularly strong electron-phonon interaction, which would give the ow carrier mobilities. From optical model for the thin film-substrate system we found the index of refraction to be 5-5.9 in the photon energy interval from 0.65 eV to 1.15 eV. There is also indication of an additional higher-energy absorption edge at 1.05 eV. $beta@- FeSi$-2$/ seems to be an intriguing material where states with energies near the band edges permit ambiguous interpretation of the character of transitions. We also present the formulae for the reflectance and transmittance for the system thin film on substrate that better reflect the experimental conditions. !27
机译:摘要:硅化铁样品是通过将蒸发到硅晶片上的铁膜退火并用非晶硅或SiO $ -x $ /薄覆盖层覆盖而形成的。通过在550度至850度的温度下退火形成半导电的FeSi $ -2 $ /相。 FeSi $ -2 $ /层的光学特性是根据在77-380K温度范围内进行的反射率和透射率测量得出的。吸收系数的光谱依赖性有利于在室温下直接允许的跃迁,禁带能隙为0.87eV。将简单的三参数半经验公式应用于直接能隙的温度依赖性会导致以下最佳拟合参数:零温度下的带隙E $ -g $ /(0)$ EQ 0.895 $ POM 0.0037eV,无量纲耦合参数S $ EQ 2.01 $ POM 0.27,以及平均声子能量。通过检查通过不同技术和热工艺制造的$ beta @ -FeSi $ -2 $ /的所有报告三元组参数,尽管0K处的带隙非常小,但晶格耦合参数和平均声子能量却存在明显差异。类似。与理论预测和较早报道的结果不同,我们的结果没有显示任何特别强的电子-声子相互作用的证据,这将使低载流子迁移。从薄膜-衬底系统的光学模型,我们发现在0.65 eV至1.15 eV的光子能量区间中,折射率为5-5.9。也有迹象表明在1.05 eV处还有一个更高的能量吸收边缘。 $ beta @-FeSi $ -2 $ /似乎是一种有趣的材料,其中在带边缘附近具有能量的状态允许对过渡特性进行模棱两可的解释。我们还提出了更好地反映实验条件的基底上系统薄膜的反射率和透射率的公式。 !27

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