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PAHS IN SEDIMENTS FROM COASTAL LAGOONS OF GULF OF MEXICO

机译:墨西哥湾沿海泻湖沉积物中的PAHS

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摘要

In this study a determination of the concentrations of 15 polycyclic aromatic hydrocarbons (PAH) in surface sediments from Salada, El Llano, La Mancha and Mandinga Lagoons, Veracruz was made during the period 1997 to 1999; these compounds were evaluated by means of gas chromatography using capillary columns of high resolution and flame ionization detection (GC-FID). The statistical results shown that differences in total concentration of PAHs during dry and rainy seasons were no significatives (p=<0.05), as well as the differences related with spatial distribution of PAHs. This is probably due to the shallowness and size of these lagoons, which are very small compared with others systems in the Gulf of Mexico. Comparison of the present results to those from other coastal systems along the Gulf of Mexico revealed that Mandinga lagoon is an area with high PAHs inputs mainly of pyrogenic origin, coming from the inflows of the rivers crossing industrial areas, oil and gasoline spills from fishing and tourism boats, the burning of surrounding vegetation and atmospheric transport. The presence of compounds made up primarily of 4 and 5 benzene rings, proves the hypothesis that the origin of the PAHs determined in all these lagoons is mainly anthropogenic. Besides the presence of 2-ring aromatic compounds in Mandinga lagoon confirms recent petrogenic inputs.
机译:在这项研究中,测定了1997年至1999年期间,韦拉克鲁斯的萨拉达,艾尔拉诺,拉曼恰和曼丁加泻湖的表层沉积物中15种多环芳烃的含量;使用高分辨率毛细管色谱柱和火焰电离检测(GC-FID),通过气相色谱法对这些化合物进行了评估。统计结果表明,干旱和雨季期间PAHs总浓度的差异无统计学意义(p = <0.05),并且与PAHs的空间分布有关。这可能是由于这些泻湖的浅浅和大小,与墨西哥湾的其他系统相比,它们很小。将当前结果与墨西哥湾沿岸其他沿海系统的结果进行比较后发现,曼丁加泻湖是一个多环芳烃输入量高的地区,主要来自热源,得益于穿越工业区的河流流入,渔业和渔业的石油和汽油泄漏。观光船,周围植被的燃烧和大气运输。主要由4和5个苯环组成的化合物的存在证明了以下假设:在所有这些泻湖中测定的PAHs的来源主要是人为的。除了在曼丁加泻湖中存在2环芳族化合物外,这也证实了最近的成岩作用。

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