Chiral Coordination Polymer: Synthesis and Application in Asymmetric Catalysis

摘要

Three chiral 1,1'-bi-2-naphthol-Ti coordination polymers were prepared. In the asymmetric oxidation of sulfide, the resulting polymers exhibited good yield and excellent enantioselectivity(up to 98%ee). The bridged-linker and the solvent was found to have a significant effect on the enantioselectivity.