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Ionic conductivity of polymer electrolyte prepareed in electrical field

机译:电场制备的高分子电解质的离子电导率

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The samples of epoxy resin-PEO400 IPN containign NaSCN salts were prepared in electric field. The conductivity was measured by impedance method. Experiment results show that the conductivity increased with increasing electric field strength in the regio nof E=0 E=20v/cm at a given temperature, and reached a maximum value, which is greater more than one order of magnitude than that of no field. After this peak, the conductivity decreased rapidly with the electric field strength above 20v/cm. The conductivity enhancement was explained by the molecular micro-structure orientation alogn the directio nof electric field. This presented a favorable passageway for ion migration. The conductivity decrease may be due to micro-structure damage by stronger field.
机译:在电场中制备了环氧树脂-PEO400 IPN含NaSCN盐的样品。通过阻抗法测量电导率。实验结果表明,在给定温度下,电导率随区域电场E = 0 E = 20v / cm的增加而增加,并达到最大值,比无电场大一个数量级。在该峰值之后,随着电场强度超过20v / cm,电导率迅速下降。电导率的提高是通过定向电场中的分子微结构取向来解释的。这为离子迁移提供了有利的途径。电导率的下降可能是由于强磁场对微结构的破坏。

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