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Non-precious Metal Electrocatalysts for Alkaline Fuel Cells

机译:碱性燃料电池的非贵金属电催化剂

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It is desirable to develop non-precious metal electrocatalysts for alkaline fuel cell (AFC). In this present work, Fe-Co-Ni/C anode catalysts were prepared by impregnating method and reduced at 900℃ under a flow of H_2 for 9 h. Alloy formation was confirmed by XRD. The maximum power density of 37 mW cm~(-2) was obtained for the cell with the Fe-Co-Ni/C anode catalyst. The NaCo_2O_4/C cathode catalysts were prepared by dry-up method. The maximum power density, 27 mW cm"2 was obtained for the cell with the NaCo_2O_4/C cathode catalyst. Though both Fe-Co-Ni/C and NaCo_2O_4/C catalysts leave much room for improvement, these results indicate that non-precious metal can be used as electrocatalyst for fuel cells.
机译:期望开发用于碱性燃料电池(AFC)的非贵金属电催化剂。本文采用浸渍法制备了Fe-Co-Ni / C阳极催化剂,在900℃的H_2气氛中还原了9h。通过XRD确认了合金的形成。对于具有Fe-Co-Ni / C阳极催化剂的电池,获得的最大功率密度为37 mW cm〜(-2)。采用干燥法制备了NaCo_2O_4 / C阴极催化剂。使用NaCo_2O_4 / C阴极催化剂的电池获得的最大功率密度为27 mW cm“ 2。尽管Fe-Co-Ni / C和NaCo_2O_4 / C催化剂都留有很大的改进空间,但这些结果表明,这种方法并不宝贵金属可用作燃料电池的电催化剂。

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