~(119)Sn Moessbauer Study of as-Deposited Layers Prepared by Co-evaporation of TeO_2 and Sn

机译：〜（119）Sn Moessbauer研究TeO_2和Sn共蒸发制备的沉积层

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The deposited layers on glass surface with thickness between 230 and 500 nm were prepared by the chemical reactions of TeO_2 and Sn during vacuum co-deposition, and were characterized as a function of the Sn/Te ratio between 0.5 and 2.8 by ~(119)Sn conversion electron Moessbauer spectroscopy. The as-deposited samples showed amorphous character with very finely dispersed microstructure. The ~(119)Sn Moessbauer spectra of as-deposited samples revealed the dominance of Sn(Ⅱ) and Sn(Ⅳ) states although SnTe was also found when the Sn/Te ratio was high. A monotonous increase of the Sn(Ⅱ)/Sn(Ⅳ) ratio was observed with increasing Sn/Te ratio.

机译：通过在真空共沉积过程中TeO_2和Sn的化学反应在玻璃表面上沉积厚度为230至500 nm的沉积层，并通过〜（119）将其表征为0.5 / 2.8之间的Sn / Te比的函数。 Sn转换电子Moessbauer光谱。沉积后的样品显示出非晶态特征，其微观结构非常分散。沉积样品的〜（119）Sn Moessbauer光谱显示了Sn（Ⅱ）和Sn（Ⅳ）态的优势，尽管当Sn / Te比很高时也发现了SnTe。随着Sn / Te比值的增加，Sn（Ⅱ）/ Sn（Ⅳ）比值出现单调增加。

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来源
《5th International Symposium on the Industrial Applications of the Moessbauer Effect Aug 13-18, 2000 Virginia Beach, Virginia》|2000年|p.251-257|共7页
会议地点 Virginia Beach VA(US);Virginia Beach VA(US)
作者
E. KUZMANN; K. NOMURA; I. PODOLESHEVA; P. GUSHTEROVA; Z. HOMONNAY; A. VERTES;
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作者单位

Department of Nuclear Chemistry, Eoetvoes University, Budapest, Hungary;

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会议组织
原文格式 PDF
正文语种 eng
中图分类一般工业技术;
关键词
~(119)Sn moessbauer spectroscopy; CEMS; Te and Sn oxide films;

机译：〜（119）Sn moessbauer光谱; CEMS; Te和Sn氧化物薄膜;
入库时间 2022-08-26 13:56:20

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~(119)Sn Moessbauer Study of as-Deposited Layers Prepared by Co-evaporation of TeO_2 and Sn

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