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Integration of Separation and Coordination Reaction of K+ in Sugar-Making Mother Liquor B on Ion-Exchange Chromatography Column

机译:离子交换色谱柱上制糖母液B中钾离子的分离和配位反应的积分

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摘要

China is severely short of Potassium resource. However, K+ is a melassigenic ion, and the high content and great melassegeniccoefficient of K+ mother liquor B in sugar-making can low sugar recoverying ratio. In order to reuse K+ in mother liquor B as a resource, a creative idea was raised to extract K+ by integrating the separation and the reaction :of K+, during the desalting of thin juice and mother liquor B. The results indicate that (1) the quality of thin juice and mother liquor B can be improved, the decalcium percentage of thin juice is greater than 90% and the de-potassium percentage is greater than 54.2% under experimental conditions; (2) the regeneration of decalcium resin using depotassium mother liquor B benefits to the de-sodium of mother liquor B; (3) the regeneration percentage of de-potassium resin is greater than 85.8% under experimental conditions; and (4) the elution of K+ on resin by the method of integrating the separation and the reaction ascribes to the attractive force and salification between SO42- and K+, and the ion exchanging between K+ on resin and Na+ in solution.
机译:中国严重缺乏钾资源。然而,K +是一种致成丝的离子,在制糖过程中,K +母液B的含量高且具有很大的成纤维系数会降低糖的回收率。为了将母液B中的K +作为资源再利用,提出了一个创意,通过在稀果汁和母液B脱盐过程中整合K +的分离和反应来提取K +。结果表明(1)在实验条件下,可以提高稀汁和母液B的质量,稀汁的脱钙百分率大于90%,脱钾百分率大于54.2%。 (2)利用钾母液B再生脱钙树脂,有利于母液B的脱钠; (3)实验条件下脱钾树脂的再生百分率大于85.8%; (4)采用分离与反应相结合的方法洗脱树脂上的K +,归因于SO42-与K +之间的吸引力和成盐作用,以及树脂上的K +与溶液中Na +之间的离子交换。

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