首页> 外文会议>1997 advanced coatings proceedings : The united new generation vehicle conference amp; exposition >Rheological Changes in Automotive Waterborne Basecoats Caused by Circulation
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Rheological Changes in Automotive Waterborne Basecoats Caused by Circulation

机译:循环引起的汽车水性底漆的流变变化

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This paper represents the first demonstration that a small laboratory system can simulate the circulation of a paint in an automotive manufacturring plant. The effect that different types of pumps and back pressure regulators (BPR) commonly used in paint circulation systems have on the flow characteristics exhibited by a non-metallic, waterborne basecoat was determined. Both rotary circumferential piston and centrifugal pumps were found to progressively change the rheological properties of the basecoat, while a double acting, reciprocating piston pump had little effect. A smaller, secondary change in the basecoat's rheological properties was found to be induced by the use of a conventional BPR as compared to a low shear BPR. The rheological changes observed to occur during circulation did not cause any significant variation in the final appearance properties exhibited by the applied automotive finish. If a measurement of a paint's viscosity is to be used by the automotive industry as a quality control tool, these measurements must be obtained at both a constant strain rate and temperature. Due to the extreme shear thinning characteristics exhibited by a waterborne basecoat, the strain rate at which this measuremnt is taken should be relatively high (i.e., >300 sec(sup)-1). The routine monitoring of viscosity at low strain rates is not recommended because of the inherent inconsistency in the measurements caused by the thixotropic nature of the paint coupled with differences in shear histroy. The use of in-line viscometry should be considered as a potential method of monitoring viscosity changes and paint quality.
机译:本文代表了一个小型实验室系统可以模拟汽车制造厂中涂料循环的首次演示。确定了涂料循环系统中常用的不同类型的泵和背压调节器(BPR)对非金属水性底漆所表现出的流动特性的影响。旋转式圆周活塞泵和离心泵都被发现会逐渐改变底漆的流变特性,而双作用往复活塞泵几乎没有作用。与低剪切BPR相比,使用常规BPR可以引起底漆流变性能的较小的二次变化。观察到在循环过程中发生的流变学变化不会导致所应用的汽车饰面漆所表现出的最终外观性能发生任何显着变化。如果汽车工业将油漆的粘度测量值用作质量控制工具,则必须在恒定的应变率和温度下获得这些测量值。由于水性底漆具有极高的剪切稀化特性,因此采用该措施的应变速率应相对较高(即> 300 sec(sup)-1)。不建议在低应变率下进行粘度的常规监测,因为由于涂料的触变性和剪切历史的差异,导致测量固有的不一致。在线粘度计的使用应被视为监测粘度变化和油漆质量的一种潜在方法。

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