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Preparation method of formamidinium lead halide perovskite quantum dots

机译:甲脒铅卤化物钙钛矿量子点的制备方法

摘要

There is provided a method of preparing formamidinium lead halide perovskite quantum dots having a photoluminescence quantum yield higher than before. The disclosed method comprises steps of: preparing a lead halide solution by dissolving lead halide (II), oleic acid and oleylamine in a nonpolar solvent; preparing a formamidinium solution by dissolving formamidine acetate salt and oleic acid in a nonpolar solvent; mixing the formamidinium solution and the lead halide solution to form quantum dots; and centrifuging the mixed solution to obtain sediment; dispersing the sediment in a nonpolar solvent to prepare a crude quantum dot solution; mixing the crude quantum dot solution with methyl acetate; and centrifuging the crude quantum dot solution mixed with the methyl acetate to obtain sediment as purified quantum dots. The durable quantum dots are stably formed by injecting the lead halide solution into the formamidinium solution heated at 60° C.-90° C.
机译:提供了一种制备甲脒卤化铅卤化物钙钛矿量子点的方法,其光致发光量子产率高于以前。 所公开的方法包括以下步骤:通过将卤化酰卤(II),油酸和油胺在非极性溶剂中溶解卤化酰卤溶液; 通过将甲脒乙酸盐和油酸溶解在非极性溶剂中,制备甲酰胺溶液; 将甲脒溶液和铅卤化物溶液混合以形成量子点; 并离心混合溶液以获得沉积物; 将沉积物分散在非极性溶剂中以制备粗量子点溶液; 将粗量子点溶液与乙酸甲酯混合; 并将粗量子点溶液与乙酸甲酯与乙酸甲酯离心以获得沉积物作为纯化量子点。 通过将卤化卤溶液注入在60℃-90℃下加热的甲脒溶液中来稳定地形成耐用的量子点。

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