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Cobalt carbide-based catalyst for direct preparation of olefin from synthesis gas, preparation method therefor and application thereof

机译:基于碳化钴的催化剂,用于从合成气中直接制备烯烃,制备方法及其应用

摘要

A cobalt carbide-based catalyst for direct production of olefin from synthesis gas, a preparation method therefor and application thereof are disclosed. The method for preparing the catalyst comprises the following steps: 1) mixing a cobalt source with water, or mixing a cobalt source, an electron promoter and water to obtain a first solution; and mixing a precipitant with water to obtain a second solution; 2) adding the first solution and the second solution to water, or water and a structure promoter for precipitation, crystallizing, separating, drying and calcination; and 3) reducing a solid obtained in Step 2) in a reducing atmosphere, and then carbonizing in a carbonizing atmosphere. The prepared catalyst has high activity and high selectivity to olefins for direct production of olefins via syngas conversion.
机译:从合成气中直接生产烯烃的基于碳化钴的催化剂,公开了一种制备方法和其应用。 制备催化剂的方法包括以下步骤:1)将钴源与水混合,或混合钴源,电子促进剂和水以获得第一溶液; 将沉淀剂与水混合以获得第二种溶液; 2)将第一溶液和第二种溶液加入水,或水和结构启动子,用于沉淀,结晶,分离,干燥和煅烧; 3)在还原气氛中减少步骤2中获得的固体,然后在碳化气氛中碳化。 制备的催化剂具有高活性和对烯烃的高选择性,用于通过合成气转化直接生产烯烃。

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