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CIRCULAR ECONOMY FOR PLASTIC WASTE TO POLYETHYLENE VIA REFINERY FCC OR FCC/ALKYLATION UNITS
CIRCULAR ECONOMY FOR PLASTIC WASTE TO POLYETHYLENE VIA REFINERY FCC OR FCC/ALKYLATION UNITS
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机译:通过炼油厂FCC或FCC /烷基化单元对聚乙烯的塑料废物循环经济
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摘要
Provided in one embodiment is a continuous process for converting waste plastic into recycle for polyethylene polymerization. The process comprises selecting waste plastics containing polyethylene and/or polypropylene, and passing the waste plastics through a pyrolysis reactor to thermally crack at least a portion of the polyolefin waste and produce a pyrolyzed effluent. The pyrolyzed effluent is separated into offgas, a pyrolysis oil and optionally wax comprising a naphtha/diesel and heavy fraction, and char. The pyrolysis oil is passed to a refinery FCC unit from which a liquid petroleum gas C3 olefin/paraffin mixture fraction is recovered, as well as a C4 olefin/paraffin mixture fraction. The liquid petroleum gas C3 olefin/paraffin mixture fraction is passed to a steam cracker for ethylene production. The C4 olefin/paraffin mixture fraction is passed to a refinery alkylation unit, from which a n-butane and naphtha feed for a stream cracker to produce ethylene is recovered.
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