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Process for the production of high purity iridium(III)chloride hydrate

机译:高纯度铱(III)氯化物的方法

摘要

Process for the production of high purity iridium(III) chloride hydrate, comprising the steps of:(1) providing at least one material selected from the group consisting of solid H2[IrCl6] hydrate, aqueous, at least 1 wt. % H2[IrCl6] solution, and solid IrCl4 hydrate;(2) adding, to the at least one material provided in step (1), at least one monohydroxy compound selected from the group consisting of monohydroxy compounds that are miscible with water at any ratio, primary monoalcohols comprising 4 to 6 carbon atoms, and secondary monoalcohols comprising 4 to 6 carbon atoms at a molar ratio of Ir(IV):monohydroxy compound=1:0.6 to 1000, and allowing to react for 0.2 to 48 hours in a temperature range from 20 to 120° C., followed by removing volatile components from the reaction mixture thus formed.
机译:用于生产高纯度铱(III)氯化物水合物的方法,包括以下步骤:(1)提供选自固体H2 [IRCL6]水合物,水性,至少1wt的基团的至少一种材料。 %H2 [IRCL6]溶液和固体IRCL4水合物;(2)加入步骤(1)中提供的至少一种材料,至少一种选自单羟基化合物的单羟基化合物,这些化合物在任何物质上由水混溶的单羟基化合物组成。 与包含4至6个碳原子的初级单醇和仲多元醇,仲多元醇,其包含Ir(iv):单羟基化合物= 1:0.6至1000的摩尔比,并允许在a中反应0.2至48小时 温度范围为20至120℃,然后从由此形成的反应混合物中除去挥发性组分。

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