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METHOD FOR PREPARING SPHERICAL SILICA POWDER FILLER, POWDER FILLER OBTAINED THEREBY AND APPLICATION THEREOF

机译:制备球形二氧化硅粉末填料的方法,得到的粉末填料及其应用

摘要

The present invention relates to a method for preparing a spherical silica powder filler. The method comprises the following steps: S1, providing spherical polysiloxane comprising a T unit by means of a hydrolytic decomposition-condensation reaction of R1SiX3, wherein R1 is a hydrogen atom or an independently selectable organic group having carbon atoms 1 to 18, X is a hydrolytic decomposition group, and the T unit is R1SiO3-; and S2, under the condition of an oxidizing gas atmosphere having a dew point greater than 10 Celsius degrees under normal pressure, calcining the spherical polysiloxane at a calcination temperature ranged between 650 Celsius degrees and 1,100 Celsius degrees to obtain a low-hardness spherical silica powder filler, the spherical silica powder filler having an uncondensed hydroxyl group. According to the spherical silica powder filler of the present invention, the hardness of silica is reduced without essentially affecting a thermal expansion coefficient of silica.
机译:本发明涉及一种制备球形二氧化硅粉末填料的方法。该方法包括以下步骤:S1,提供借助于R 1 六个 3 的水解分解 - 缩合反应的球形聚硅氧烷,其中R 1 是具有碳原子1至18的氢原子或独立选择的有机基团,x是水解分解基团,T单位为R 1 SiO 3 - ;并且S2在常压下露点大于10摄氏度的氧化气体气氛的条件下,在煅烧温度下煅烧球形聚硅氧烷,范围在650摄氏度和1,100摄氏度之间以获得低硬度球形二氧化硅粉末填充物,具有未调用的羟基的球形二氧化硅粉末填料。根据本发明的球形二氧化硅粉末填料,二氧化硅的硬度降低而不基本上影响二氧化硅的热膨胀系数。

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