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BaTiO3 BaTiO3-Cu High density BaTiO3-Cu composite films with optimized BaTiO3 matrix for embedded capacitors

机译:BATIO3 BATIO3-CU高密度BATIO3-CU复合膜,具有优化的BATIO3嵌入式电容器矩阵

摘要

A high-density BaTiO 3 -Cu composite film with a BaTiO 3 matrix for embedded capacitors is disclosed. In order to improve the dielectric properties and areal capacitance according to the percolation theory, 0 to 50 wt% of Cu was used as a metal filler of the BaTiO 3 (BT) matrix. A BT-Cu composite film with a thickness of 2 μm was formulated using aerosol deposition at room temperature for use in embedded-film capacitors. The flow conditions of the carrier gas are varied to create very compact composite films without surface craters and internal voids, resulting in relatively high dielectric constant, relatively low dielectric loss, and relatively low leakage current. leakage current) was achieved. The BaTiO 3 -Cu composite film showed a highly dense microstructure and smooth surface, and good dielectric properties were observed when the carrier gas was supplied at 10 L/min. The dielectric constant of the BaTiO 3 -Cu composite film increased with the increase of the Cu content. Although the dielectric loss and leakage current also increased with Cu content, the Cu density in the BaTiO 3 -Cu composite film was within acceptable limits until it reached 40 wt %, and the 40 wt % Cu-containing film was found in previous studies. It exhibited a high areal capacitance, approximately five times the reported values. Additionally, a percolation threshold was observed for composite films with 45 wt % Cu. Despite the advent of the percolation threshold, the BT-Cu composite films all showed low frequency dependence, as the formation of micro-capacitor structures dominated their interior.
机译:公开了一种高密度BATIO 3 -CU复合膜具有用于嵌入电容器的BATIO 3 基质。为了改善根据渗透理论的介电性能和面积电容,将0至50wt%的Cu用作 BaTiO 3(BT)基质的金属填料。 A BT-Cu复合材料在室温下使用气溶胶沉积配制厚度为2μm的薄膜用于嵌入膜电容器。载气的流动条件改变以产生具有表面凹槽和内部空隙的非常紧凑的复合膜,导致相对高的介电常数,相对低的介电损耗和相对低的漏电流。达到漏电流。 BATIO 3 -Cu复合膜显示出高度致密的微观结构和光滑的表面,并且当载气在10L / min供应时观察到良好的电介质性质。随着Cu含量的增加,BATIO 3 -Cu复合膜的介电常数增加。虽然介电损耗和漏电流也随Cu含量增加,但是BATIO 3 -Cu复合膜中的<亚Cu密度在可接受的限度内,直至其达到40重量%,并含40wt%的Cu在以前的研究中发现了电影。它表现出高度的面积电容,报告的价值观约为五倍。另外,对于具有45wt%Cu的复合膜,观察到渗透阈值。尽管存在渗透阈值的出现,但是BT-Cu复合膜都显示出低频依赖性,因为微电容结构的形成主导了它们的内部。

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