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SILICONE-ACRYLATE COPOLYMERS, AND RELATED METHODS AND COMPOSITIONS

机译:硅氧烷丙烯酸酯共聚物,以及相关方法和组合物

摘要

A curable composition is disclosed. The curable composition comprises (I) an epoxide-functional silicone-acrylate polymer and (II) an aminosiloxane. The epoxide-functional silicone-acrylate polymer comprises acrylate-derived monomeric units comprising siloxane moieties, epoxide-functional moieties, and optionally, hydrocarbyl moieties, and the aminosiloxane comprises an average of at least two amine functional groups per molecule. A method of preparing the curable composition is also disclosed, and includes reacting (A) an acryloxy-functional organosilicon component, (B) an epoxy-functional acrylate component, and optionally (C) an acrylate component, to give the epoxide-functional silicone-acrylate polymer (I), and combining the epoxide-functional silicone-acrylate polymer (I) with the aminosiloxane (II). An aminosiloxane-silicone-acrylate copolymer prepared with the composition, a cured product comprising the same, and methods of preparing the same, are also disclosed.
机译:公开了一种可固化的组合物。可固化组合物包含(I)环氧化物 - 官能硅氧烷 - 丙烯酸酯聚合物和(II)氨基硅氧烷。环氧化物功能性硅氧烷 - 丙烯酸酯聚合物包含丙烯酸酯衍生的单体单元,其包含硅氧烷部分,环氧官能部分和任选的烃基部分,并且氨基硅氧烷每分子的平均至少两种胺官能团。还公开了一种制备可固化组合物的方法,并包括使(a)丙烯酰氧基官能团组分,(b)环氧官能丙烯酸酯组分,以及任选的(c)丙烯酸酯组分,得到环氧官能硅氧烷 - 与氨基硅氧烷(II)合并环氧化物官能硅氧烷 - 丙烯酸酯(I)。还公开了一种用组合物制备的氨基硅氧烷 - 硅氧烷 - 丙烯酸酯共聚物,其包含相同的固化产物和制备方法。

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