首页> 外国专利> TWO-PART CURABLE URETHANE ADHESIVE, CURED PRODUCT OF TWO-PART CURABLE URETHANE ADHESIVE, AND URETHANE ADHESIVE SHEET

TWO-PART CURABLE URETHANE ADHESIVE, CURED PRODUCT OF TWO-PART CURABLE URETHANE ADHESIVE, AND URETHANE ADHESIVE SHEET

机译:两部分可固化氨基甲酸酯粘合剂,两部分固化氨基甲酸酯粘合剂固化产物,和氨基甲酸酯粘合片

摘要

The purpose of the present invention is to provide a two-part curable urethane adhesive whereby it is possible to obtain an adhesive sheet that exhibits excellent cured film properties, can be peeled off with very little force, and exhibits little change in adhesive strength before and after a heat resistance test. The present invention is a two-part curable urethane adhesive including a main agent and a curing agent, wherein the main agent includes a urethane resin (P) that has a hydroxyl group and is obtained by reacting a polyol component (a) that has a polyfunctional polyoxyalkylene polyol (a1) having a hydroxyl value of 10-350 mgKOH/g as an essential component with a urethane prepolymer (b) having an isocyanate group. The polyfunctional polyoxyalkylene polyol (a1) is a polyoxyalkylene polyol (a11) having a hydroxypropyl group on the end of the molecule represented by general formula (1) and/or an ethylene oxide addition product (a12) thereof, and the curing agent includes a crosslinking agent (D) having an isocyanate group. In general formula (1), X is an m-valent residue obtained by removing all of the active hydrogen atoms from a compound having m of active hydrogen atoms, A is an alkylene group that has 2-12 carbons atoms and that may be substituted with a phenyl group, a halophenyl group, or a halogen atom, Z is a propylene group, m is an integer of 4-10, p is an integer of 0-199, q is an integer of 1-200, and the expression 1 ≤ p + q ≤ 200 is satisfied.
机译:本发明的目的是提供一种两部分可固化的氨基甲酸酯粘合剂,由此可以获得具有优异的固化膜性能的粘合片,可以用非常小的力去剥离,并且在之前的粘合强度变化很小在耐热试验之后。本发明是一种双部分可固化的氨基甲酸酯粘合剂,包括主要剂和固化剂,其中所述主要试剂包括具有羟基的聚氨酯树脂(P),并通过使具有a的多元醇组分(a)反应获得具有10-350mgKOH / g的多官能聚氧化烯多元醇(A1),为具有异氰酸酯基团的聚氨酯预聚物(B)的必需组分。多官能聚氧化烯多元醇(A1)是具有通式(1)和/或其环氧乙烷加成产物(A12)表示的分子末端的羟丙基的聚氧化烯多元醇(A11),并且固化剂包括a具有异氰酸酯基团的交联剂(D)。在通式(1)中,X是通过从具有活性氢原子的含量的化合物除去所有活性氢原子而获得的M型残留物,A是具有2-12个碳原子的亚烷基并且可以被取代通过苯基,卤素基或卤素原子,Z是丙烯基,M是4-10的整数,P是0-199的整数,Q是1-200的整数,表达式和表达式满足1≤p+q≤200。

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