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Light-colored rosin and rosin ester compositions
Light-colored rosin and rosin ester compositions
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机译:浅色松香和松香酯组合物
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摘要
A three-step method to prepare a light-colored rosin ester is disclosed wherein at least in one of the steps (a) and (c) a co-catalyst is applied and wherein at least in one of the steps (a) and (c) a disproportionation catalyst is applied. In the second step, a distilled rosin is obtained which is esterified with a polyol into a light-colored rosin ester. In one embodiment, the co-catalyst has a triplet formation quantum yield (ϕT) of greater than 0.5 and a triplet lifetime (τT) of greater than 0.5 microseconds. In another embodiment, the co-catalyst is selected from acridone, anthrone, 9-fluorenone, thioxanthone, xanthone, derivatives and combinations thereof.
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机译:公开了一种制备浅色松香酯的三步方法,其中至少在步骤(a)和(c)中的一个中施加副催化剂,并且至少在步骤(a)中的一个和( c)施加歧化催化剂。在第二步中,获得蒸馏松香,其用多元醇酯化成浅色松香酯。在一个实施方案中,助催化剂具有大于0.5的三重型形成量子产率(φ<亚> t sub>),并且三重寿命(τ t sub>)大于0.5微秒。在另一个实施方案中,助催化剂选自吖啶,蒽酮,9-芴酮,噻吨酮,X吨酮,衍生物及其组合。
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