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POLYETHYLENE COMPOSITION AND FILM HAVING HIGH STIFFNESS, OUTSTANDING SEALABILITY AND HIGH PERMEABILITY

机译:聚乙烯组合物和薄膜具有高刚度,优异的密封性和高渗透性

摘要

A polyethylene composition comprises a first polyethylene which is an ethylene copolymer having a weight average molecular weight of from 70,000 to 250,000 and a molecular weight distribution Mw/Mn of < 2.3, a second polyethylene which is an ethylene copolymer or homopolymer having a weight average molecular weight of from 15,000 to 100,000, a molecular weight distribution Mw/Mn of > 2.3, and a third polyethylene which is an ethylene copolymer or homopolymer having a weight average molecular weight of from 70,000 to 250,000 and a molecular weight distribution Mw/Mn of > 2.3, where the first polyethylene has more short chain branching than the second polyethylene or the third polyethylene. The polyethylene composition has a soluble fraction in a CEF analysis of at least 10 weight percent. Film made from the polyethylene composition may have a machine direction 1% secant modulus of ≥ 200 MPa (at a film thickness of about 1 mil), a seal initiation temperature (SIT) of ≤ 90°C (at a film thickness of about 2 mil), an area of hot tack window (AHTW) of ≥ 160 Newtons∙C° (at a film thickness of about 2 mil) and an oxygen transmission rate (OTR) of ≥ 600 cm3 per 100 inch2 (at a film thickness of about 1 mil).
机译:聚乙烯组合物包含第一聚乙烯,其是重均分子量为70,000至250,000的乙烯共聚物,以及<2.3的分子量分布Mw / Mn,第二聚乙烯,其是具有重均分子的乙烯共聚物或均聚物重量为15,000至100,000,分子量分布Mw / Mn> 2.3和第三聚乙烯,其是重均分子量为70,000至250,000的乙烯共聚物或均聚物,以及分子量分布Mw / Mn 2.3,其中第一聚乙烯具有比第二聚乙烯或第三聚乙烯更短的链支化。聚乙烯组合物在至少10重量%的CEF分析中具有可溶性级分。由聚乙烯组合物制成的薄膜可具有≥200mPa的机器方向1%均匀模量(在约1密耳的膜厚度),密封发起温度(Sit)≤90℃(薄膜厚度为约2米尔),热粘性窗口(AHTW)的区域≥160牛顿∙C°(在约2密耳的薄膜厚度)和≥600cm 3 每次的氧传输速率(OTR) 100英寸 2 (在薄膜厚度为约1密耳)。

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