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Method for preparing single-walled carbon nanotube flexible transparent conductive film with carbon welded structure

机译:用碳焊接结构制备单壁碳纳米管柔性透明导电膜的方法

摘要

A single-walled carbon nanotube flexible transparent conductive thin film with a carbon welded structure and a preparation method therefor. In the process of growing a single-walled carbon nanotube by means of floating catalyst chemical vapor deposition, the concentrations of a catalyst and a carbon source and the residence time thereof in the constant temperature region are reduced, so that part of the carbon source decomposed by means of the catalyst forms an sp2 carbon island which is welded at the intersection of individual single - walled carbon nanotubes, and finally, a single-walled carbon nanotube thin film with an sp2 carbon island welded structure is formed. The thin film of the structure has better photoelectric properties, chemical stability and flexibility than the ITO thin film on a flexible substrate. The contact resistance between carbon nanotubes is reduced, the formation of tube bundles and a large absorption of light are inhibited, and a high-performance flexible transparent conductive thin film is obtained by designing and preparing the individual carbon nanotubes bonded by means of a carbon welded structure. The high-performance flexible transparent conductive thin film is of great significance for promoting the application of a carbon nanotube thin film in the field of high-performance optoelectronic devices.
机译:一种单壁碳纳米管柔性透明导电薄膜,碳焊接结构及其制备方法。在通过浮动催化剂化学气相沉积生长单壁碳纳米管的过程中,减少了催化剂和碳源及其停留时间的浓度,使得部分碳源分解借助于催化剂,形成在单壁碳纳米管的交叉点处焊接的SP2碳岛,最后,形成具有SP2碳岛焊接结构的单壁碳纳米管薄膜。该结构的薄膜具有更好的光电性能,化学稳定性和柔性比柔性基板上的ITO薄膜。减小碳纳米管之间的接触电阻,抑制了管束的形成和大吸收光,通过设计和制备借助于碳焊接的单独的碳纳米管来获得高性能柔性透明导电薄膜结构体。高性能柔性透明导电薄膜对于促进碳纳米管薄膜在高性能光电器件领域中的应用具有重要意义。

著录项

  • 公开/公告号JP6845259B2

    专利类型

  • 公开/公告日2021-03-17

    原文格式PDF

  • 申请/专利权人 中国科学院金属研究所;

    申请/专利号JP20180564954

  • 发明设计人 侯 鵬翔;蒋 松;劉 暢;成 会明;

    申请日2017-06-06

  • 分类号C01B32/159;C01B32/162;B01J31/22;B82Y30;B82Y40;H01B5/14;H01B13;

  • 国家 JP

  • 入库时间 2022-08-24 17:44:04

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