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Anion exchange resin, method for producing thereof, electrolyte membrane for fuel cell, binder for forming electrode catalyst layer, fuel cell electrode catalyst layer and fuel cell

机译:阴离子交换树脂,其制备方法,用于燃料电池的电解质膜,形成电极催化剂层的粘合剂,燃料电池电极催化剂层和燃料电池

摘要

Provided are an anion exchange resin being capable of producing an electrolyte membrane for a fuel cell, a binder for forming an electrode catalyst layer and a fuel cell electrode catalyst layer, which have an improved physical property (anion conductivity); a method for producing thereof; an electrolyte membrane for a fuel cell, a binder for forming an electrode catalyst layer and a fuel cell electrode catalyst layer produced from the anion exchange resin; and a fuel cell having the electrolyte membrane or the electrode catalyst layer.;For example, the anion exchange resin is obtained by reacting a hydrophobic monomer with an aminoalkyl group-containing monomer, in which the hydrophobic monomer is composed of one aromatic ring or a plurality of aromatic rings to which two halogen atoms are bonded, and the aminoalkyl group-containing monomer is composed of one aromatic ring or a plurality of aromatic rings to which two halogen atoms are bonded and an aminoalkyl group is introduced; and by quaternizing the amino group. In the anion exchange resin, a divalent hydrophobic group formed by the residue of the hydrophobic monomer, and a divalent hydrophilic group formed by the residue of the quaternized aminoalkyl group-containing monomer are bonded via direct bond.
机译:提供了一种阴离子交换树脂,其能够为燃料电池生产电解质膜,用于形成电极催化剂层的粘合剂和具有改进的物理性质(阴离子电导率)的燃料电池电极催化剂层;一种生产方法;用于燃料电池的电解质膜,用于形成电极催化剂层的粘合剂和由阴离子交换树脂制备的燃料电池电极催化剂层;和具有电解质膜或电极催化剂层的燃料电池。例如,通过用含氨基烷基的单体反应疏水性单体来获得阴离子交换树脂,其中疏水性单体由一个芳环或a组成键合的多个芳环,并且含氨基烷基的单体由一个芳环或多个卤素原子键合的芳环构成,并引入氨基烷基;并通过季铵化氨基。在阴离子交换树脂中,通过直接键键合通过疏水式单体残余物和由含季铵化氨基烷基单体的残余物形成的二价亲水基团形成的二价疏水基。

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